通過更近對(duì)市場(chǎng)的調(diào)查回訪我們發(fā)現(xiàn)，很多客戶對(duì)順酐的制備方法還不是了解的很明白，今天小編就將查閱的相關(guān)資料與大家分享一下，希望引起大家的重視，讓大家對(duì)
順酐有一個(gè)深層次的了解。這樣大家在購買使用順酐時(shí)也能做到心中有數(shù)，不怕上當(dāng)受騙，希望對(duì)大家有所啟發(fā)與幫助。 Through the recent market survey and return visit, we found that many customers don't understand the preparation method of Shandong maleic anhydride very well. Today, the editor will share the relevant information with you, hoping to attract your attention and let you have a deep understanding of Shandong maleic anhydride. In this way, when you purchase and use Shandong maleic anhydride, you can also have a clear idea, not afraid of being cheated, and hope to inspire and help you.
1. 苯氧化制山東順酐
1. Oxidation of benzene to Shandong maleic anhydride
將苯與空氣混合（苯為1%-1.4% ）經(jīng)換熱器預(yù)熱后，進(jìn)人列管式催化反應(yīng)器。在壓力為0.1-0.2MPa、溫度為350-400℃的反應(yīng)條件下進(jìn)行氧化反應(yīng)，所得產(chǎn)物經(jīng)兩臺(tái)換熱器、一臺(tái)冷卻器后，冷卻到接近露點(diǎn)（55―65℃）。冷卻后的反應(yīng)物進(jìn)入分離器，分離器底部得粗順酐，進(jìn)入粗順酐罐。分離器頂部流出物進(jìn)人洗滌塔，用水洗滌，塔頂為多余空氣和未反應(yīng)的苯，苯可用吸附回收。洗滌塔塔底水溶液進(jìn)人脫水器，分離出水，所得粗順酐進(jìn)人粗順酐罐。粗順酐進(jìn)一步進(jìn)人蒸餾塔進(jìn)行蒸餾精制，得順酐。所得山東順酐可進(jìn)行異構(gòu)化得富馬酸和蘋果酸。
The mixture of benzene and air （benzene is 1% - 1.4%） is preheated by heat exchanger and then put into the tubular catalytic reactor. The oxidation reaction was carried out at the pressure of 0.1-0.2mpa and the temperature of 350-400 ℃。 The product was cooled to the dew point （55-65 ℃） by two heat exchangers and one cooler. The cooled reactant enters the separator, and the crude maleic anhydride is obtained at the bottom of the separator and enters the crude maleic anhydride tank. The effluent from the top of the separator enters into the washing tower and is washed with water. The top of the tower is redundant air and unreacted benzene, which can be recovered by adsorption. The bottom water solution of the washing tower enters into the human dehydrator, the separated water, and the obtained crude maleic anhydride enters into the human crude maleic anhydride tank. Crude maleic anhydride is further distilled into a distillation tower to obtain maleic anhydride. The maleic anhydride can be isomerized to fumaric acid and malic acid.
2.C4餾分部分氧化制順酐
2. Partial oxidation of C4 fraction to maleic anhydride
工業(yè)上用不經(jīng)分離的C4餾分或分離異丁烯和丁二烯后的C4餾分為原料順酐。C4餾分與空氣混合后進(jìn)人流化床氧化反應(yīng)器，在300―500℃溫度下，與反應(yīng)器中的催化劑接觸順酐。氧化反應(yīng)器頂部流出的反應(yīng)生成物進(jìn)人吸收塔，用水作為吸收劑，塔頂氣體經(jīng)廢水
Maleic anhydride is produced from C4 fraction without separation or C4 fraction after separation of isobutylene and butadiene. C4 fraction is mixed with air and then enters the fluidized bed oxidation reactor. At 300-500 ℃， it contacts with the catalyst in the reactor to produce maleic anhydride. The reaction products from the top of the oxidation reactor enter the absorption tower, and water is used as the absorbent. The gas from the top of the tower flows through the waste water
